If you are using the Site option from the upper menu bar, the pages need to be open within DreamWeaver in order for the Put option to display. You can also click the Put button(upper arrow) or right click the file name and select Put from the popup menu from the Files screen. This does not require the files to be open.
In either case, ensure you have properly added the correct server information for FTP as well.
We have an article for publishing with Dreamweaver, but it's for CS5. However, they may be similar to what you are seeing:
Publishing with Dreamweaver CS5
If you have any further questions, please contact technical support or leave a comment at the bottom of the page.
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