I'll be happy to assist you! You can set up in the Merchant Services section of PayPal to direct your customer to a page after they purchase, but not automatically send them an email with the eBook.
To have an email sent automatically, you will need to use a script. There are some programs designed to help with this step, such as Tradebit at http://www.tradebit.com/ (Note that I have not used that site but it was one recommended on a few reviews I read), which will simplify the process. I guess the quick answer to your question is that it is possible, but not through Paypal to automatically send the email to the customer. If you have any other questions just let us know!
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