Thanks for the question. You would not really be setting up a mail relay because you still want to have mail delivered to our server here. You're talking more about split delivery where some email will go to the Web Hosting Hub server and some to the Google App email server. We do not typically support this, BUT you can add a nother email server with a different priority to the list so that mail can be processed through Google's mail server. Here is their documentation for these options: Configure Split Delivery
There's also this article on Mail routing and delivery. I also asked around about it hear and our systems guy said that this was what you needed. You will need to get familiar with making MX changes using the cPanel MX Records application.
I hope that helps to answer your question. Please let us know if you have any further questions.
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